Corrosion inhibition of carbon steel using novel N-(2-(2-mercaptoacetoxy)ethyl)-N,N-dimethyl dodecan-1-aminium bromide during acid pickling

A novel cationic surfactant, N-(2-(2-mercaptoacetoxy)ethyl)-N,N-dimethyl dodecan-1-aminium bromide, has been synthesized to study its corrosion inhibiting effect against carbon steel in 1.0 M HCl solution. The corrosion inhibition efficiency was measured by using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, and weight loss methods. The inhibition efficiencies obtained from these methods were in good agreement. The inhibition efficiency slightly decreased in the temperature range 30–60 °C. The synthesized inhibitor acted as a mixed inhibitor. Thermodynamic adsorption and activation parameters were discussed. Adsorption of the synthesized inhibitor was found to follow the Langmuir adsorption isotherm. A chemical adsorption mechanism is proposed.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Novel cationic surfactant is good corrosion inhibitor for carbon steel in 1.0 M HCl. ► The polarization studies indicated that the inhibitor acted as a mixed type inhibitor. ► Adsorption of the inhibitor is chemical adsorption and obeyed Langmuir isotherm. ► The inhibition efficiency increased with concentration and temperature increasing. ► Novel cationic surfactant exhibited good surface properties.