Corrosion behaviour of a 2219 aluminium alloy treated with a chromate conversion coating exposed to a 3.5% NaCl solution

This study investigates the formation of a chromate conversion coating at Al–Cu–Fe–Mn intermetallic sites of an Al2219 alloy and the corrosion initiation at these sites in a 3.5% NaCl solution, using SEM, AES and EDX. Changes in the surface chemistry were monitored after progressive exposures to the solution up to 42 h. The coating was found to be thinner and more defective on the intermetallic. Initially, Al is dissolved and Al(OH)3 deposited on and around the intermetallic. After 42 h of exposure, Al(OH)3, Fe and Mn oxides and small particles of elemental Cu are deposited as corrosion products.

Research highlights► Alodine 1200S coating is thinner on intermetallics than on the alloy matrix. ► Corrosion of Al2219 involves oxidation of Al but also of Fe and Mn. ► After 42 h exposition to a corrosive medium there is back-deposition of metallic Cu.