Article ID Journal Published Year Pages File Type
1470537 Corrosion Science 2011 5 Pages PDF
Abstract

An ultrafine-grained (UFG) Ni3Al was fabricated by annealing an electrodeposited Ni–Al composite in vacuum at 600 °C for 2 h. The UFG Ni3Al, compared to a compositional-similar but coarse-grained (CG) alloy prepared by arc-melting, exhibited a greatly increased cyclic oxidation resistance at 900 °C. Microstructural investigation showed that the CG alloy grew a scale with a high susceptibility to buckling and cracking because of the formation of large voids at the scale/metal interface, but that the UFG alloy grew an adherent scale, because its typical structure prevented the formation of the interface void during oxidation.

Research highlights► An ultrafine-grained Ni3Al with dispersions of ultrafine pores is developed. ► The UFG Ni3Al grew an adherent alumina scale during cyclic oxidation at 900 °C. ► The UFG structure helps to prevent large interface void formation during oxidation. ► Distribution of fine pores in UFG Ni3Al does not affect the alumina scale adhesion. ► Alumina scale on arc-melted Ni3Al spalled due to the large interface void formation.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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