Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1472169 | Corrosion Science | 2007 | 9 Pages |
Abstract
An experimental set-up for the investigation of particle induced flow corrosion is described. It allows high speed monitoring of the repassivation current transient resulting from the impingement of a single particle. High purity aluminium microelectrodes with a diameter of 125 μm were used as targets in a neutral acetate buffer. Zirconia spheres of similar diameter were impinged at a flow rate of 7 m sâ1. After an activation period of about 6 μs the current reaches a peak current of 10 μA. The current returns to its initial base line within one millisecond. Subsequent ex situ investigation of the samples in a SEM allows linking the detected surface destruction to its current transient. A crater of some 20 μm diameter is observed that shows a nanoscopic substructure resulting from the nanostructure of the particle. Part of the repassivation charge must be determined by an extrapolation of the high field oxide growth. A comparison of the consumed charge to the microscopic observations gives insights into the destruction mechanisms.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Achim Walter Hassel, Andrew J. Smith,