Article ID Journal Published Year Pages File Type
1473451 Journal of the European Ceramic Society 2016 9 Pages PDF
Abstract

Electric conduction and dielectric relaxation behavior in (1—x)(Bi0.5Na0.5TiO3-BaTiO3)-xNaNbO3 ((1—x)(BNT–BT)–xNN) ceramics were investigated. All compositions showed negative temperature coefficient of resistance (NTCR) behavior. The bulk conductivity followed the Arrhenius law with Ea = 1.24–1.55 eV, which can be attributed to the electronic conduction. In the modulus (M′′-f) spectra, a peak and a shoulder were observed, corresponding to the bulk and polar nano regions (PNRs) response respectively. With the increase of either temperature or NN content, the shoulder gradually depressed and even disappeared. A correlation between the PNRs evolution and the relaxation behavior was constructed.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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