Article ID Journal Published Year Pages File Type
1475990 Journal of the European Ceramic Society 2013 11 Pages PDF
Abstract

Hot pressing has been investigated for the production of transparent MgAl2O4 aimed at the scaling up of the process. Other assessed techniques (hot isostatic pressing, spark plasma sintering) can hardly be used for the production of flat components with large dimensions and good planarity.Hot pressing of stoichiometric Al2O3–MgO powder mixtures has been preferred to the direct pressing of spinel powder for the readily availability of pure powders and to exploit the thermodynamic driving force of the spinel formation. LiF has been used as sintering additive.A thermodynamic investigation of the reactions involving LiF, MgO and Al2O3 has helped in the comprehension of the densification mechanisms affecting the transparency of spinel. Transparencies up to 70% in the visible range (highest value 78% at 1100 nm) have been obtained. Suitable soakings have been added for promoting the initial liquid phase sintering and the release of LiF through formation of vapour phases.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
Authors
, , ,