Low temperature preparation and electrical properties of sodium–potassium bismuth titanate lead-free piezoelectric thick films by screen printing

Sodium–potassium bismuth titanate (NKBT) thick films with thickness of 40 μm were prepared by screen printing. To improve the homogeneity, the sintering aids were added into the pastes as a chemical liquid-phase doping method. The results show that the addition of Bi–Li sintering aids was beneficial for both the reduction of the sintering temperature and the improvement of the electrical performance of the thick films. The thick films containing 5 wt.% Bi–Li sintering aids demonstrated optimal dielectric properties with the maximum dielectric constant of 725 and minimum dielectric loss of 2.5%. Moreover, the NKBT thick films containing 3 wt.% Bi–Li sintering aids sintered at 950 °C exhibited the remanent polarization of 19.6 μC/cm2, room-temperature pyroelectric coefficient of 1.56 × 10−4 C/(m2 °C), figure of merit for specific detectivity of 0.48 × 10−5 Pa−0.5, and effective longitudinal piezoelectric coefficient of 88 pm/V, which are comparable to that of the high-temperature sintered thick films without sintering aids.