| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1477756 | Journal of the European Ceramic Society | 2008 | 6 Pages |
Abstract
The aim of the presented work was to study formation of magnesium aluminate spinel precursor powder during the co-precipitation of magnesium and aluminium nitrate with ammonium carbonate and its thermal transformation to spinel powder. After precipitation, the only crystalline phase is NH4Al(OH)2CO3·H2O (ammonium dawsonite). The second one, Mg6Al2(CO3)(OH)16·4H2O (hydrotalcite) appears during ageing. As found by DTA-MS and HT-XRD measurements, co-existence of both phases in very close contact results in their easier decomposition. On the base of the results obtained the scheme of phase transformations of co-precipitated precursor leading to formation of MgAl2O4 is proposed.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Anna Wajler, Henryk Tomaszewski, Ewa Drożdż-Cieśla, Helena Węglarz, Zbigniew Kaszkur,