Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1487696 | Materials Research Bulletin | 2015 | 5 Pages |
•Co2Z-type hexaferrites were sintered in different atmospheres.•The losses of the sample sintered in O2 were reduced effectively without additive.•A 3RC equivalent circuit model was put forward in the impedance analysis.
Co2Z-type hexaferrites with stoichiometric composition of Ba3Co2Fe24O41 were fabricated by using a conventional solid–state reaction method. The influence of sintering atmosphere, namely air, O2 and N2, on magnetic and electrical properties of the hexaferrites was systematically investigated. This work reveals that O2 played an important role in inhibiting the formation of Fe2+ and thus reducing magnetic and dielectric losses. The Co2Z specimen sintered at 1300 °C in O2 atmosphere showed promising magneto-dielectric properties. Specifically, the magnetic and dielectric losses were less than 0.05 and 0.005 in the frequency range of 30–300 MHz, respectively. Impedance spectra were performed to reveal the underlying mechanisms for the different electrical properties of the Co2Z ceramics sintered in different atmospheres.
Graphical abstractOxygen atmosphere played an important role in inhibiting electrons hopping between Fe2+ and Fe3+ and reducing both of magnetic and dielectric losses of Ba3Co2Fe24O41, which is favorable in view of antenna substrate applications.Figure optionsDownload full-size imageDownload as PowerPoint slide