Article ID Journal Published Year Pages File Type
1488418 Materials Research Bulletin 2014 4 Pages PDF
Abstract

•CeO2:Er/Yb nanorods exhibit better upconversion property.•The luminescence intensities of the red emissions are higher than the green ones.•The upconversion luminescence intensities are proportional to the excited power.•The mechanism of upconversion luminescence involves the ET and ESA.

CeO2:Er/Yb nanorods as upconversion materials were successfully synthesized by solvothermal method. The structures and morphologies of the CeO2:Er/Yb nanorods were characterized by XRD, SEM, HRTEM. The nanorods emitted two kinds of visible lights: the green (2H11/2, 4S3/2 ⟶ 4I15/2) and the red (4F9/2 ⟶ 4I15/2), under excitation with a continuous wave laser in the near-infrared at 980 nm at room temperature. The mechanism of different emissions was explored involving excited-state absorption (ESA) and energy transfer (ET) upconversion.

Graphical abstractCeO2:Er/Yb nanorods were synthesized by solvothermal method. The nanorods emitted two kinds of visible lights: the green (2H11/2, 4S3/2 ⟶ 4I15/2) and the red (4F9/2 ⟶ 4I15/2) under excitation with a continuous wave laser at 980 nm. The luminescence intensities are proportional to the excited power and the intensities of the red emissions are higher than the green ones.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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