| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1488452 | Materials Research Bulletin | 2014 | 5 Pages |
•Highly textured SCNN ceramics were prepared by RTGG method in this work.•The electrical properties of textured SCNN ceramics in both c-axis and a-axis directions were studied.•The electrical properties comparison of textured SCNN ceramics in c-axis direction with random SCNN ceramics was studied.•The formation mechanism of higher texture quality in SCNN ceramics was discussed.
Highly textured Sr1.85Ca0.15NaNb5O15 (SCNN) ceramics with enhanced electrical properties were successfully prepared by the reactive templated grain growth method using acicular Sr2KNb5O15 (SKN) template particles. Through carefully controlling the processing conditions, a texture fraction of 0.88 was obtained when the ceramics were sintered at 1340 °C for 6 h. The obtained textured SCNN ceramics exhibited obvious anisotropic properties with the highest electrical properties shown in c-axis direction: ɛr = 2270, ɛm = 5902, Tc = 247 °C, tan δ = 0.014, Pr = 16.88 μC/cm2 and d33 = 162 pC/N. These properties were superior to those of randomly oriented SCNN ceramics with the same composition, showing that fabricating lead-free ceramics through reactive templated grain growth method is an effective way to achieve superior performance for commercial application. In addition, the formation mechanism of higher texture quality in SCNN ceramics was discussed in detail.
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