Article ID Journal Published Year Pages File Type
1488695 Materials Research Bulletin 2013 5 Pages PDF
Abstract

The AlN-doped BaMgAl10O17:Eu2+ phosphors were synthesized by conventional solid-state reaction. Powder X-ray diffraction (XRD), scanning electron microscope (SEM) and photoluminescence spectrum (PL) were used for characterization. The growth mechanism was carried out by computer simulation with CASTEP application, and revealed that an ideal hexagonal shape, particle size in 5 μm and 2.5–3 μm in thickness, could be obtained by AlN doping. Additionally, due to the low electronegativity of N3−, the AlN-doped sample showed 35% increase in PL intensity and improvement of thermal stability. These fine particle size and better photoluminescence properties are expected to be applicable to industrial production of BaMgAl10O17:Eu2+ phosphors.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Ideal hexagonal shape particle size in 5 μm and 2.5–3 μm in thickness are obtained. ► The growth mechanism is studied by a computer simulation. ► The influence of introduced AlN on the sites of Eu2+ and photoluminescence properties was investigated.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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