Intercalation of IR absorber into layered double hydroxides: Preparation, thermal stability and selective IR absorption

N-phosphonomethyl aminodiacetic acid (PMIDA) was intercalated into the interlayer spacing of layered double hydroxides (LDH) by an anion-exchange method. The intercalated LDHs were characterized by various techniques such as powder X-ray diffraction (XRD), FT-IR spectroscopy, elemental analysis and simultaneous thermogravimetric and mass spectrometry (TG-MS) in details. The results show the formation of Mg2Al-PMIDA LDH based on the expansion of d-spacing from 0.89 nm to 1.22 nm and the disappearance of the characteristic IR absorption band at 1384 cm−1 for NO3− anions. The incorporation of Mg2Al-PMIDA LDH into the low density polyethylene (LDPE) as an additive enhances the selectivity of IR absorption in the main wavelength region 9–11 μm for radiant heat loss at night. Mg2Al-PMIDA LDH as a heat-retaining additive has practical application in agricultural plastic films.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► PMIDA anions were intercalated into Mg2Al-NO3 LDH by anion-exchange method. ► The prepared material has highly selective IR absorption property in 9–11 μm. ► The obtained material has practical applications as heat-retaining additive.