| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1489769 | Materials Research Bulletin | 2012 | 5 Pages |
In this paper, effect of NH4Cl flux concentrations (0, 1, 2, 3 and 4 wt%) on the crystal structure, morphology and photoluminescent properties of Sr2SiO4:Eu3+ phosphors synthesized by a microwave sintering at 1200 °C for 1 h was investigated and discussed. X-ray powder diffraction analysis showed the crystal structure was not affected and the pure Sr2SiO4 phase was formed without second phase or phases of starting materials when adding with the NH4Cl flux. The SEM images indicated that increase of the NH4Cl flux enlarged the particle size of the phosphor particles. The photo-luminescence results showed the addition of 1 wt% NH4Cl flux much improved the emission intensity at λem of 617 nm as the excitation spectrum at λex of 395 nm. The decay times of Sr2SiO4:Eu3+ phosphors with different NH4Cl flux concentrations were obtained around 2.47–2.52 ms.
Graphical abstractThis paper describes effects of NH4Cl concentration on microstructural and luminescent characteristics of Sr2SiO4:Eu3+ phosphors using microwave assisted sintering at 1200 °C for 1 h. The results showed the improved photoluminescence properties of microwave sintered Sr2SiO4:Eu3+ phosphors by adding NH4Cl flux.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► NH4Cl flux improved the luminescence properties of microwave sintered phosphors. ► The particle sizes were enlarged from 1 μm to 10 μm as the NH4Cl flux was added. ► The maximum photoluminescence intensity was appeared as adding 1 wt% NH4Cl flux. ► The decay times of Sr2SiO4:Eu3+ phosphors with NH4Cl flux were around 2.47–2.52 ms.
