| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1489866 | Materials Research Bulletin | 2013 | 7 Pages |
A modified laser zone remelting was performed to prepare novel crack-free bulk Al2O3/Er3Al5O12(EAG) oxide in situ composite thermal emission ceramics, aiming to investigate the influence of rapid solidification on the ceramic melting process and microstructure characteristics. The grown Al2O3/EAG ceramic showed a near full density value of >99% and smooth surface, and it was sensitive to rapid solidification. The density increased with decreasing laser scanning rate, which led to a decrease of smoothness in surface finishing. At low scanning rate of 20 μm/s, fine faceted-grown EAG phases of 1–2 μm were homogeneously embedded in the Al2O3 matrix, presenting typical irregular patterned lamellar microstructures. The eutectic spacing was rapidly refined with the increase of laser scanning rate due to high temperature gradient and rapid solidification rate. The minimal spacing was reduced below 300 nm. Furthermore, at high scanning rate the faceting growth tendency was decreased and particular dendrite eutectic structures were produced, whose formation mechanisms were discussed.
Graphical abstractMicrostructure evolution of LZR Al2O3/EAG eutectic ceramic grown at different laser scanning rates: (a) 20 μm/s, cross-section; (b) 600 μm/s, cross-section; (c) 20 μm/s, longitudinal section; (d) 600 μm/s, longitudinal section.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Preparing near full density Al2O3/EAG eutectic ceramics by laser zone remelting. ► The eutectic growth is closely related to rapid cooling rate of laser remelting. ► Ultra-fine irregular microstructure with eutectic spacing below 300 nm is obtained. ► Faceted growth tendency of eutectic phases decreases with increasing growth rate. ► Particular band and dendrite eutectic structures are found at high scanning rate.
