Preparation and hydrothermal annealing of pure metastable β-MnS thin films by chemical bath deposition (CBD)

Pure metastable β-MnS thin films have been deposited by chemical bath deposition (CBD) method and subsequently annealed in a Na2S solution (denoted as hydrothermal annealing). The effects of preparative parameters and hydrothermal annealing on structure, morphology and optical property of the films have been investigated. Experimental results indicate that the crystalline β-MnS thin films can be prepared at a low concentration of Mn and S ions without using any organic chelator. The as-deposited β-MnS can be transformed to γ-phase MnS after the hydrothermal treatment in an autoclave at 200 °C for 1 h. The estimated Eg values are in the range of 3.15–3.18 eV.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights▶ Pure β-MnS thin films were successfully prepared by CBD method at the low concentration of Mn and S ions without organic chelator. ▶ The crystallization of the as-deposited MnS thin film was carried out in a Na2S solution at 200 °C. ▶ The as-deposited CBD β-MnS could be transformed to γ-MnS through hydrothermal treatment.