Synthesis and photocatalytic activity of mesoporous cerium doped TiO2 as visible light sensitive photocatalyst

Cerium doped titania materials were synthesized varying the cerium concentration from 0 to 10 wt%. Materials are characterised by XRD, TEM, XPS and N2 adsorption desorption method. Surface area and visible light absorption substantially increases and crystallite size decreases with the increasing cerium content. Cerium doping stabilizes the anatase phase and surface area even at 600 °C calcination. Photocatalytic activity towards methylene blue decomposition and selenium (IV) reduction is found to increase with the cerium content up to 5 wt% and then decreases. Materials calcined at 600 °C shows better activity than that calcined at 400 °C, even though surface area decreases. Anatase crystallinity mostly decides the photocatalytic activity rather than only surface area. It can be concluded that the optimum visible light absorption and oxygen vacancy with 5% cerium doping enhances the photocatalytic activity. In addition photocatalytic performance is found to depend on the presence of Ce4+/Ce3+ rather than only visible light absorption.

Graphical abstractCerium doped titania having optimum 5 wt% of cerium can decompose methylene blue and reduce selenium (IV) efficiently under visible light.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Effect of cerium doping on the surface properties and visible light mediated photocatalytic reaction is studied. ► Cerium doping increases the anatase phase stability, surface area (up to 137 m2/g) and visible light absorption. ► Importance of Ce3+/Ce4+, oxygen vacancy, surface area and crystallinity is correlated with improved catalytic activity. ► Material with 5 wt% Ce is found to be most active photocatalyst for methylene blue decomposition and Se (IV) reduction.