| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1490658 | Materials Research Bulletin | 2012 | 4 Pages |
A novel and high-performance palladium-based catalyst for Heck reaction was prepared easily by the co-precipitation method. The catalyst was characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), vibrating sample magnetometry (VSM), X-ray photoelectron spectroscopy (XPS) and atomic absorption spectrophotometry (AAS). The catalyst afforded a fast conversion of the 4-bromonitrobenzene to 4-nitrostilbene at a catalyst loading of 5 mol%, and the efficiency of the catalyst remains unaltered even after 6 repeated cycles. The excellent catalytic performance of the Pd/Fe3O4 catalyst might be attributed to the enhanced synergistic effect between Pd nanoparticles and magnetite.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Palladium-based heterogeneous catalyst was prepared facilely via the co-precipitation method. ► The particles are nearly spherical in shape with an average size of 20 ± 1.0 nm. ► The developed magnetic catalyst showed high activity for Heck reaction. ► The catalyst was easily recovered from the reaction mixture with external magnetic field. ► The catalytic efficiency for Heck reaction remains unaltered even after 6 repeated cycles.
