| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1490755 | Materials Research Bulletin | 2011 | 5 Pages |
The transport and magnetic properties of the double perovskite compounds Ca2Fe1−xCoxMoO6 (0.1 ≤ x ≤ 0.4) have been explored through resistivity [ρ(T)], dc magnetisation [M(H, T)] and ac susceptibility [χ(T, f)] measurements. Introduction of Co increases the lattice volume implying the divalent nature of cobalt in this system. For all the samples, ρ(T) behaviour over the temperature range (25–273 K) can be adequately described by considering possible disorder-enhanced electron–electron interaction effect as well as spin-wave contribution. Our results reveal that with the increase of Co concentration, the ferromagnetic Curie temperatures (TC) gradually reduced due to the incorporation of antiferromagnetic Co2+–Mo6+ pairs replacing ferromagnetic Fe3+–Mo5+ pairs. A cluster-glass like behaviour is also observed in the system due to the presence of highly spin-disordered regions.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► We have presented the crystallographic, electrical transport and dc and ac magnetic measurements on double perovskite Ca2Fe1−xCoxMoO6 (0.1 ≤ x ≤ 0.4) system. ► Co exists in divalent state in these compounds. ► The substituted system exhibits cluster-glass like behaviour, close to that observed earlier in Sr2Fe1−xCoxMoO6 compatible with an electronic phase segregation scenario (Phys. Rev. B 73 (2006) 104417).
