Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1491631 | Materials Research Bulletin | 2009 | 6 Pages |
Abstract
(Zn2+/Mg2+)[Fe3+]2O4 spinel oxides can be refined as direct/fully inverted (respectively) spinels but considering cationic and anionic vacancies and/or interstitial atoms instead of a partial inversion rate of the A2+ and B3+ cations. The refinements results of the X-ray diffraction patterns and Mössbauer spectroscopy spectra are discussed and show the veracity of the new structural formalism.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
M. Gaudon, N. Pailhé, A. Wattiaux, A. Demourgues,