Article ID Journal Published Year Pages File Type
1492185 Materials Research Bulletin 2005 9 Pages PDF
Abstract

Chemical preparation, crystal structure, IR absorption and thermal analysis of a new cyclotetraphosphate [2-NH2-5-CH3C5H4N]4P4O12·6H2O are reported. This compound is triclinic P-1 with unit-cell parameters: a = 10.206(5), b = 11.778(1), c = 9.991(4) Å, α = 110.40(6), β = 117.74(6), γ = 86.41(3)°, V = 989.1(8) Å3, Z = 1, Dx = 1.445 g cm−3. The structure has been determined and refined to R = 0.034 and Rw = 0.044, using 3663 independent reflections. The P4O124− ring anions and water molecules form layers spreading around (a, b + c) planes via OH⋯O hydrogen bonds. Between them are anchored 2-amino-5-methylpyridium cations, which establish H-bonds to interconnect the different adjacent layers and so contribute to the cohesion of the three-dimensional network. Tautomerization of (C6H9N2)+ groups was evidenced in the present structure.

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Physical Sciences and Engineering Materials Science Ceramics and Composites
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