Synthesis and characterization of polyaniline nanorods/Ce(OH)3–Pr2O3/montmorillonite composites through reverse micelle template

Polyaniline (PANI) nanorods/Ce(OH)3–Pr2O3/montmorillonite (MMT) nanocomposites were synthesized via in situ polymerization of aniline monomer through reverse micelle template (RMT) in the presence of montmorillonite and Ce(OH)3, Pr2O3. In the experiment, sulphosalicylic acid was used as dopant, aniline was designated as oil phase and the aqueous solution comprising Ce3+ and Pr3+ as water phase. The nanocomposites were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) analysis, Fourier transform infrared (FT-IR) spectroscopy and thermogravimetry–differential thermal analysis (TG–DTA). The results showed that PANI nanorods were synthesized in the interlayer spaces of MMT with uniform spherical rare earth nanoparticles. The thermal stability of the nanocomposites prepared was enhanced drastically compared with pure polyaniline.