| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1492430 | Materials Research Bulletin | 2006 | 9 Pages |
Abstract
Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wwR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.
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Authors
Shilie Pan, Jared P. Smit, Michael R. Marvel, Charlotte L. Stern, Byron Watkins, Kenneth R. Poeppelmeier,