Article ID Journal Published Year Pages File Type
1493270 Optical Materials 2016 5 Pages PDF
Abstract

•The synthesis of schiff bases were obtained by condensation of o-tolidine with salicylaldehyde and cinnamaldehyde.•The obtained ligands were characterized by UV, 1H and NMR.•Third-order NLO properties were measured using the third harmonic generation technique on thin films at 1064 nm.•Frontier molecular orbital analysis is provided.

This paper explores the synthesis, structure characterization and optical properties of two new schiff bases. These compounds were obtained by condensation of o-tolidine with salicylaldehyde and cinnamaldehyde. The obtained ligands were characterized by UV, 1H and NMR. Their third-order NLO properties were measured using the third harmonic generation technique on thin films at 1064 nm. The electric dipole moment (μ), the polarizability (α) and the first hyperpolarizability (β) were calculated using the density functional B3LYP method with the lanl2dz basis set. For the results, the title compound shows nonzero β value revealing second order NLO behaviour.

Keywords
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
Authors
, , , , , , , , , ,