Article ID Journal Published Year Pages File Type
1493439 Optical Materials 2015 4 Pages PDF
Abstract

•X-ray luminescence of LiLa1−xNdxP4O12 nanocrystals were investigated.•The influence of size of nanocrystals on X-ray luminescence is presented.•The impact of Nd3+ concentration on X-ray luminescence is analyzed.

X-ray luminescence properties of LiLa1−xNdxP4O12 nanocrystals were investigated for the first time. The influence of the Nd3+ concentration on the integral emission intensities in visible and near infrared emission region were investigated. It was found that emission from 2F(2)5/2 is strongly affected by cross-relaxation process and its intensity decreases exponentially with Nd3+ amount, while emission from 4F7/2 + 4S3/2, 4F5/2 + 2H11/2, and 4F3/2 states rises up sublinearly with Nd3+ concentration. The size effect on emission spectra under X-ray excitation was presented.

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Physical Sciences and Engineering Materials Science Ceramics and Composites
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