| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1493736 | Optical Materials | 2015 | 7 Pages |
•Investigations of absorption and luminescence properties of Bi2ZnOB2O6:Pr crystals.•The spectroscopic properties were analyzed using the Judd–Ofelt theory.•Bi2ZnOB2O6:Pr crystals may be used as a new generation laser frequency converters.
Nonlinear optical Bi2ZnOB2O6 single crystals doped with Pr3+ ions were grown using the Kyropoulos method. The absorption and luminescence properties of these new systems were investigated for the first time. The crystals are characterized by the large values of nonlinear optical coefficients. Effective luminescence of the Pr3+ ions makes this system an excellent candidate for the near-infrared (NIR) and/or ultraviolet (UV) to visible (VIS) laser converters. Based on the obtained experimental spectroscopic data, detailed analysis of the absorption and luminescence spectra was performed using the conventional Judd–Ofelt theory. Those transitions, which can be potentially used for laser applications of the Pr3+ ion, have been identified. In addition to the intensity parameters Ω2, Ω4, Ω6 the branching ratios and radiative lifetimes were estimated for all possible transitions in the studied spectral region.
