Article ID Journal Published Year Pages File Type
1494844 Optical Materials 2013 4 Pages PDF
Abstract

Rare earth elements (Pr, Ce) doped ternary sulfides of formula RbGd1−xRExS2 were synthesized in the form of crystalline hexagonal platelets by chemical reaction under the flow of hydrogen sulfide. The X-ray powder diffraction detected only a single crystalline phase of rhombohedral lattice system. Optical properties of studied systems are investigated by methods of time-resolved luminescence spectroscopy. Thermal stability of the Pr3+ emission is demonstrated. Application potential in the white light-emitting diode solid state lighting or X-ray phosphors is discussed.

► We report structural and luminescence characteristics of the RbGdS2-based phosphors. ► Pr3+ and Ce3+ luminescence features in RbGdS2 were measured in 8–500 K interval. ► We investigate the influence of Ln3+ (Ln = La, Gd, and Lu) in RE-doped RbLnS2. ► The application potential of studied materials in white LEDs is discussed.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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