| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1494857 | Optical Materials | 2013 | 5 Pages |
Highly crystalline YOF:Ln3+ (Ln = Yb, Er, Tm) microboxes were successfully synthesized for the first time by using a mixed NaNO3–KNO3 flux cooling method at a holding temperature of 600 °C for 2 h in air. The results indicated that the as-obtained products belonged to tetragonal system and exhibited microboxes morphology with side lengths of 0.5–2 μm. The upconversion luminescence properties of as-prepared YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ were investigated in detail. Under 980 nm laser diode (LD) excitation, the emission intensity and the corresponding luminescence colors of YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ could be precisely adjusted by changing the doping concentration of Yb3+ ions. Furthermore, the paper also offers a new alternative in synthesizing such materials and opens the possibility to meet the increasing commercial demand.
► YOF:Ln3+ microboxes were successfully synthesized for the first time. ► The mixed NaNO3–KNO3 flux cooling method was adopted. ► Multicolor UC emissions of YOF:Yb3+/Er3+ microboxes can be achieved. ► The intense NIR emission in YOF:Yb3+/Tm3+ microboxes is obtained.
