| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1494909 | Optical Materials | 2013 | 5 Pages |
•Sr2CeO4: Eu3+, Dy3+ phosphors were synthesized by a polymer-network gel method.•The photoluminescence properties of Eu3+ and Dy3+ in Sr2CeO4 were investigated.•The PL mechanism cannot be explained only by the energy transfer model.•The defect conditions in crystals were also considered to clarify the PL mechanism.
We report single-phased color-tunable phosphors (Sr2CeO4: Eu3+, Dy3+) synthesized by a polymer-network gel method for UV–LED. The photoluminescence properties and possible energy transfer mechanisms of Eu3+ and Dy3+ in Sr2CeO4 were investigated by experiments and first principles calculations. The results show that the 5D0 → 7F2 emission of Eu3+ is enhanced by the increase in the amount of Eu3+ ions and Eu3+ substitution makes more stable defect than Dy3+ substitution does. The photoluminescence mechanism of Sr1.994−xEuxDy0.006CeO4 can be explained by the energy transfer model with the consideration of the defect conditions in the crystals.
Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (136 K)Download as PowerPoint slide
