Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1495895 | Optical Materials | 2010 | 4 Pages |
Abstract
MgxSr1−xAl2O4:Eu, Dy (x = 0.05–0.25) phosphors were prepared by the solid-state reaction method; their excitation and emission spectra corresponding to the transitions between the ground 4f7 and excited 4f65d1 configurations of Eu2+ ion were studied. Broad band UV excited luminescence attributed to Eu2+ ions was observed around 19,500 cm−1 (513 nm). From the comparison between the excitation and emission spectra, the crystal field splitting of the Eu2+ 5d states and the parameters of electron–vibrational interaction, such as the Huang–Rhys factor, effective phonon energy, and zero-phonon line position for the studied compound were estimated for the first time.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
K.S. Bartwal, H. Ryu, M.G. Brik, I. Sildos,