| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1495995 | Optical Materials | 2011 | 5 Pages |
Er3+/Yb3+ doped strontium titanate borosilicate glass was prepared. Glass ceramic was prepared by controlled heat treatment (at 955 °C) of glass. Ti10O19 and Sr3Ti2O7 were found as major crystalline phases. The emission spectra of glass and glass ceramic samples were investigated under 976 nm laser excitation. In glass ceramic, the intensity of the emitted radiation was much higher (≈50 times for green and ≈10 times for red emission) than in the glass. A new three photon process was found to be responsible for emission at low power which is not yet observed in Er3+/Yb3+:SrO⋅TiO2 glass ceramic system to the best of our knowledge. The details of upconversion mechanisms e.g. Energy Transfer (ET) and Excited State Absorption (ESA) were studied by power-intensity log dependence. It is expected that Er3+/Yb3+ doped nanocrystalline (⩽10 nm) Sr3Ti2O7 phase was responsible for the observed upconversion phenomenon in glass ceramic.
► Er3+/Yb3+:SrO⋅TiO2 borosilicate optical active glass and glass ceramic were prepared. ► The major crystalline phases in glass ceramic are Sr3Ti2O7 and Ti10O19. ► The nano particles of Sr3Ti2O7 are distributed homogeneously. ► Upconversion emission intensity is much more in the glass ceramic than glass. ► Difference in the photon processes is explained with the help of a theoretical model.
