Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1497908 | Progress in Solid State Chemistry | 2009 | 16 Pages |
Abstract
Lithium intercalation in oxides is a topic of capital importance for the development of lithium batteries materials. We review herein the lithium insertion process involved in different structures 3D, 2D and 1D. In most of the cases, starting from an anionic cubic close packed array, the topotactic process of alkaline ion insertion, associated with a biphasic process in the potential-composition electrochemical curve, generates an ordered rock salt type structure for the fully reduced phase. Such a behavior allowed us to imagine other fully lithiated compositions that could show really good electrochemical behavior toward the lithium insertion/deinsertion.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
V. Pralong,