Article ID Journal Published Year Pages File Type
1498053 Scripta Materialia 2016 6 Pages PDF
Abstract

A detailed invariant line analysis was described on the habit plane and orientation relationship between TiO2(B) and anatase in titania nanocrystalline photocatalyst. It is demonstrated that the predicted habit plane and orientation relationship are coincident well with the observed crystallographic features. The polymorphic phase transformation of C-centred monoclinic structure to body-centred tetragonal structure is proposed to start from an initial Bain lattice correspondence that close-packed plane of matrix is parallel to close-packed plane of product, so is closed-packed direction.

Graphical abstractA possible transformation mechanism was proposed that the closed-packed plane (001) and closed-packed vector [010] of C-centred monoclinic structure keeps invariant in orientation when transforming into body-centred tetragonal structure.Figure optionsDownload full-size imageDownload high-quality image (169 K)Download as PowerPoint slide

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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