Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1498321 | Scripta Materialia | 2015 | 4 Pages |
Abstract
Nanocrystalline YDC thin films with grain-sizes ranging from 38 to 93-nm were prepared using pulsed laser deposition followed by thermal annealing. Ionic conductivity decreased up to four orders of magnitude as the grain size increased. Using energy-dispersive X-ray spectroscopy, we showed that the counter-intuitive reduction in conductivity with grain-size is likely due to dopant and impurity segregation near grain-boundaries. Spectroscopic evidence suggests that the blocking effect due to defect segregation is more dominant on ionic conductivity than the grain-sizes.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Jihwan An, Jiwoong Bae, Soonwook Hong, Bongjun Koo, Young-Beom Kim, Turgut M. Gür, Fritz B. Prinz,