Article ID Journal Published Year Pages File Type
1498946 Scripta Materialia 2013 4 Pages PDF
Abstract

The atomic-scale defect structures in Mn-doped (1 − x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMNT) single crystal have been investigated by using X-ray absorption fine structure analysis. Temperature-dependent diffusive dielectric loss peaks as a doping effect were found for Mn-doped PMNT. Combined with these experiments the structure of dipolar defects was confirmed. There is an oxygen vacancy around Mn2+ ions, and vacancy and ion interact strongly to form the charge-dipole [(MnTi2+)″-VO]. The dipolar defects will pin the domain walls, thereby reducing the dielectric loss of the crystals.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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