Article ID Journal Published Year Pages File Type
1500760 Scripta Materialia 2010 4 Pages PDF
Abstract

A systematic study of hydrogenated amorphous silicon nitride films deposited by varying gas flow rate ratio (R = SiH4/NH3) using Photo-Chemical Vapour Deposition reveal that as R is increased, dominant phase changes from silicon oxynitride to silicon nitride with embedded silicon nanoclusters. The change in photoluminescence spectral features in these films is attributed to quantum confinement effect. The results suggest that hydrogen plays a crucial role in overall phase evolution and in-situ formation of Si nanoclusters embedded in silicon nitride matrix.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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