Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1500833 | Scripta Materialia | 2009 | 4 Pages |
Abstract
While evidence of ion reduction at the cathode has been given, proof of anode activity, in order to account completely for the redox-type electrochemical mechanism so far postulated to originate the electric field-induced non-spontaneous crystallization observed in glasses, is still lacking. This study demonstrates that direct contact of both cathode and anode electrodes with the material is mandatory to promote crystal nucleation. The electrochemical process of concern is established here to involve a solid-state process, electrolytic in nature.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
J.-C. M’Peko, J.E. De Souza, A.C. Hernandes,