Article ID Journal Published Year Pages File Type
1502268 Scripta Materialia 2006 4 Pages PDF
Abstract

Formation abilities of perovskite-type hydrides in Ca1+xT–H, where T = 3d transition metals and x = 0–1.0, were examined. CaNiH3 and CaCoH3 were found to form the cubic perovskite structure. In the former hydride, the maximum amount of Ni vacancy is estimated to be approximately 20%, CaNi0.8H3, using powder neutron diffraction measurements. The thermal desorption processes of CaT–H for T = Fe, Co or Ni were investigated by the relationship between perovskite- and complex-type hydrides.

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Physical Sciences and Engineering Materials Science Ceramics and Composites
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