Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1502700 | Scripta Materialia | 2009 | 4 Pages |
Abstract
We investigated the influence of the substrate on the thermodynamic properties of metal hydride thin films by hydrogenography, using PdHx as a model system. After appropriate hydrogen cycling, reproducible hydrogenation properties are found at the same equilibrium pressure for all substrates studied. Comparing these thin films with free-standing films—measured both by hydrogenography and by Sievert’s method—we find a very similar behavior. Hence, thin films can be used to study the hydrogenation behavior of the corresponding bulk materials.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Y. Pivak, R. Gremaud, K. Gross, M. Gonzalez-Silveira, A. Walton, D. Book, H. Schreuders, B. Dam, R. Griessen,