Heterogeneous nucleation of Mg–Al alloys

Grain size is one of the most important microstructural characteristics determining the mechanical properties and therefore the service performance of polycrystalline materials. Heterogeneous nucleation involves the addition or in situ formation of potent nuclei in the system to promote nucleation events, leading to a fine grain structure. This paper reports experimental results using graphite and SiC as potential grain refining agents to form in situ nuclei for Mg in Mg–Al alloys, and demonstrates the key role of Al4C3 in grain refining this important alloy system. This insight will contribute to the design and development of the most cost effective, eco-friendly grain refining agents for Mg–Al alloys.