Article ID Journal Published Year Pages File Type
1503270 Scripta Materialia 2007 4 Pages PDF
Abstract

Three preparation methods – quenching, sintering and annealing – have been employed to synthesize Y-filled skutterudite compounds YxCo4Sb12 (0.00 ⩽ x ⩽ 0.35). Y atoms do not fill the vacancy sites in the skutterudite structure in the form of YxCo4Sb12. YSb and CoSb2 are formed as impurity phases when Y is added. The lattice thermal conductivity is reduced by 30% by Y addition, indicating that the segregated impurity phases strongly scatter.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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