Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1503291 | Scripta Materialia | 2007 | 4 Pages |
Abstract
Well-crystallized Mg(BH4)2 was chemically synthesized and the effect of ball milling and Ti-based additives on the dehydriding properties were investigated. The dehydriding reaction of the as-synthesized Mg(BH4)2 initiates at approximately 535 K and about 13.7 mass% of hydrogen is desorbed. Compared with the as-synthesized Mg(BH4)2, few changes are observed in the samples after ball milling, while the initial dehydriding temperature of Mg(BH4)2 is significantly reduced by the addition of TiCl3, i.e. from 535 K down to 361 K.
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Authors
H.-W. Li, K. Kikuchi, Y. Nakamori, K. Miwa, S. Towata, S. Orimo,