| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1503436 | Scripta Materialia | 2006 | 4 Pages |
Abstract
This paper reports the microstructure of LiXPO4 (X = Ni, Co, Mn) materials prepared by solid state chemical reaction. The variation in microstructure of these phospho-olivines is mainly due to a difference in the XO6 cationic octahedral environment, which is discussed using a molecular vibration model to elucidate the bonding between various structural units. A direct relationship is established between the vibrational frequencies and the second ionisation potential of the metal (X) in LiXPO4.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
C.M. Julien, A. Ait Salah, F. Gendron, J.F. Morhange, A. Mauger, C.V. Ramana,