Article ID Journal Published Year Pages File Type
1503638 Scripta Materialia 2006 5 Pages PDF
Abstract

Photo-induced mechanical properties of two copolymer thin films with 3.5 and 6 mol% azobenzene chromophores in the side chain, were investigated by nanoindentation. After ultraviolet irradiation the stiffness of the films was found to increase by about 10–28% compared to their original ‘virgin’ state. The altered mechanical properties were attributed to conformational changes in the polymer chains via a trans–cis isomerisation of the chromophores.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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