Defect induced nickel, nitrogen-codoped mesoporous TiO2 microspheres with enhanced visible light photocatalytic activity

•Visible light photocatalysis.•Trap level.•Oxygen vancancies.•Substitutional and interstitial N.

Nickel, nitrogen-codoped mesoporous TiO2 microspheres (Ni–N–TiO2) with high surface area, and an effective direct band gap energy of ∼2.58 eV. Nickel sulfate used as the Ni source and ammonia gas as the N source here. The efficiency of the as-prepared samples was investigated by monitoring the degradation of Rhodamine B under visible light irradiation. The experimental results indicate that Ni-doped mesoporous TiO2 microspheres show higher photocatalytic activity than mesoporous TiO2 microspheres under visible light irradiation. It mainly due to that the electron trap level (Ni2+/Ni+) promoting the separation of charge carriers and the oxygen vacancies inducing the visible light absorption. In addition, Ni–N–TiO2 shows enhanced activity compared with Ni–TiO2. Codopants and dopants are found to be uniformly distributed in TiO2 matrix. Among the all samples the 0.5% molar quantity of Ni dopant and 500 °C 2 h nitriding condition gives the highest photocatalytic activity. The treatment of ammonia gas on Ni–TiO2 sample induced oxygen vancancies, substitutional and interstitial N. A suitable treatment by ammonia gas also promote separation of charge carriers and the absorption of visible light. The active species generated in the photocatalytic system were also investigated. The strategy presented here gives a promising route towards the development of a metal and non-metal codoped semiconductor materials for applied photocatalysis and related applications.

Graphical abstractNickel, nitrogen-codoped mesoporous TiO2 microspheres (Ni–N–TiO2) with high surface area, and an effective direct band gap energy of ∼2.58 eV. The efficiency of the as-prepared samples was investigated by monitoring the degradation of Rhodamine B under visible light irradiation. Among the all samples the 0.5% molar quantity of Ni dopant and 500 °C 2 h nitriding condition gives the highest photocatalytic activity. The treatment of ammonia gas on Ni–TiO2 sample induced oxygen vancancies, substitutional and interstitial N. A suitable treatment by ammonia gas also promote separation of charge carriers and the absorption of visible light. The strategy presented here gives a promising route towards the development of a metal & non-metal codoped semiconductor materials for applied photocatalysis and related applications.Figure optionsDownload full-size imageDownload as PowerPoint slide