| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1504315 | Solid State Sciences | 2014 | 5 Pages |
•LiCu2O2 is a low dimensional frustrated magnet, antiferromagnetic below 25 K.•LiCu2O2 belongs to the family of magnetoelectric cuprates.•Structural properties were investigated in detail in the 12–295 K temperature range.•A correlation between structural and magnetic properties is evidenced above 25 K.
Temperature-dependent crystallographic and magnetic studies on stoichiometric single crystals of LiCu2O2 are reported. The temperature dependence of the lattice parameters was extracted from X-ray powder diffractograms collected on crushed single crystals, from 12 K to 295 K. The magnetic properties are similar to earlier findings demonstrating antiferromagnetic ordering below 25 K. Evidence of magnetoelastic coupling is observed in the thermal expansion along the c-direction; not only at the low temperature antiferromagnetic transitions, but an anomalous behavior of the thermal expansion indicate magnetoelastic coupling also to the magnetic ordering related to a weak spontaneous magnetic moment appearing at 150 K. Ac-susceptibility measurements at different frequencies and superposed dc-fields are employed to further characterize this magnetic anomaly.
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