Urchin-like cobalt incorporated manganese oxide OMS-2 hollow spheres: Synthesis, characterization and catalytic degradation of RhB dye

Urchin-like KxCoyMn8−yO16 hollow spheres assembled from nanoplate building blocks were successfully fabricated via a one-pot hydrothermal route using cobalt acetate and potassium permanganate as raw material. The products were characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectrometer, field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and high resolution transmission electron microscopy (HRTEM) measurement. The thermal stability and surface areas of cobalt ion in the manganese sites of KMn8O16 structures were clearly evidenced by TGA and N2 adsorption–desorption isotherms curves. Based on time depended experiment results, a possible formation mechanism for this structures was proposed. The catalytic degradation of Rhodamine B (RhB) on KxCoyMn8−yO16 materials has, therefore been dependent for the molar precursor ratio and specific surface area of the as-fabricated products. UV–vis, LC–MS and barium hydroxide methods were utilized to monitor the temporal course of the catalytic reaction.

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