| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1505675 | Solid State Sciences | 2009 | 6 Pages |
Abstract
When anionic clay like nickel zinc hydroxyacetate was subjected to anion exchange reaction with either hexacyanoferrate(II) or hexacyanoferrate(III) ions, the complex anion intercalation was accompanied by auto redox reactions. In both the cases a mixture of hexacyanoferrate(II) and hexacyanoferrate(III) ions was found to be intercalated in the anionic clay. The mixed anion intercalated anionic clays could be oxidized by hydrogen peroxide to get pure hexacyanoferrate(III) intercalated anionic clay. Thermal decomposition of the intercalated anionic clays yields mixed oxides of Ni, Zn and Fe.
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Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Jacqueline T. Rajamathi, N.H. Raviraj, Mohammed F. Ahmed, Michael Rajamathi,