Article ID Journal Published Year Pages File Type
1505832 Solid State Sciences 2011 5 Pages PDF
Abstract

Two new compounds, [(C4H9)4P]2[Cu5I7] and [(C4H9)4P]2[Cu5I7]·CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7]2− cluster. It displays a molecular symmetry very close to C2. Both compounds crystallize in space group P21/c.

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Physical Sciences and Engineering Materials Science Ceramics and Composites
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