| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1506086 | Solid State Sciences | 2009 | 7 Pages |
Abstract
A molecular salt with formula [BmIm]3[PMo12O40]3− has been prepared using room temperature ionic liquid and phosphomolybdic acid. The material is characterized by single-crystal X-ray diffraction. The compound crystallizes in orthorhombic system with space group Pca21. It is also characterized by CHN analysis, 31P MAS NMR, UV–vis DRS and near-IR methods. Thermal stability of the compound is investigated by TGA, IR and PXRD methods. Near-IR shows the loss of water of crystallization by the Keggin ions of phosphomolybdic acid bonded with ionic liquid.
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Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
G. Ranga Rao, T. Rajkumar, Babu Varghese,